Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation

نویسندگان

  • Lars C. Grabow
  • Qiuyi Yuan
  • Hieu A. Doan
  • Stanko R. Brankovic
چکیده

Available online 3 April 2015

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Ag/Pt Core-Shell Nanoparticles on Graphene Nanocomposite for Effective Anodic Fuels Electro-oxidation

The nanocomposite consists of the Ag as a core and Pt as shell on the surface of graphene nanosheets (Ag/Pt-G) was synthesized with a simple method and used as a novel electrochemical platform for an efficient catalyst for oxidation of the ethanol, methanol and formic acid. The morphology and electrochemical properties of Ag/Pt-G nanocomposite were investigated by TEM, X-ray diffraction, and vo...

متن کامل

Enhanced Catalytic Activity of Pt-NdFeO3 Nanoparticles Supported on Polyaniline-Chitosan Composite Towards Methanol Electro-Oxidation Reaction

In this work, NdFeO3 nanoparticles were synthesized through a simple co-precipitation method. The formation of NdFeO3 particles was verified by X-ray powder diffraction, infrared spectroscopy, vibrating sample magnetometer, and transmission electron microscopy analysis. Polyaniline and chitosan were employed as proper support for production of metal nanoparticles. Novel Pt...

متن کامل

Mild activation of CeO2-supported gold nanoclusters and insight into the catalytic behavior in CO oxidation.

We report a new activation method and insight into the catalytic behavior of a CeO2-supported, atomically precise Au144(SR)60 nanocluster catalyst (where thiolate -SR = -SCH2CH2Ph) for CO oxidation. An important finding is that the activation of the catalyst is closely related to the production of active oxygen species on CeO2, rather than ligand removal of the Au144(SR)60 clusters. A mild O2 p...

متن کامل

Electro-catalytic oxidation of CO on Pt catalyst supported on carbon nanotubes pretreated with oxidative acids

Characteristics of nanosized Pt electro-catalyst deposited on carbon nanotubes (CNTs) were studied with CO-stripping voltammogram and chronoamperometry measurements. The CNTs were pretreated by oxidation in HNO3, mixed HNO3 + H2SO4 and H2SO4 + K2Cr2O7 solution, respectively, to enable surface modification. Well-homogenized Pt particles (average size: 3 nm) were loaded onto the pretreated CNT sa...

متن کامل

Ethanol electrooxidation on the Co@Pt core-shell nanoparticles modified carbon-ceramic electrode in acidic and alkaline media

In this study, the electrocatalytic activity of the Co@Pt core-shell nanoparticles toward the ethanol oxidation reaction has been investigated by cyclic voltammetry and chronoamperometry in acidic and alkaline media in details. The physicochemical data obtained in alkaline solution are compared to those in acidic solution. The obtained results demonstrate that while in the both media Co@Pt core...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2015